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1 article(s) from Wang, Wentao

Heterogeneous photocatalytic cyanomethylarylation of alkenes with acetonitrile: synthesis of diverse nitrogenous heterocyclic compounds

Guanglong Pan,
Qian Yang,
Wentao Wang,
Yurong Tang and
Yunfei Cai

Beilstein J. Org. Chem. 2021, 17, 1171–1180, doi:10.3762/bjoc.17.89

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Scheme 1: CN-K-Catalyzed cyanomethylarylation of alkenes to access diverse heterocyclic compounds.

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Scheme 2: CN-K-catalyzed cyanomethylarylation of N-arylallylamines for the synthesis of indolines. Reaction c...

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Scheme 3: CN-K-catalyzed cyanomethylarylation of N-benzoylallylamines for the synthesis of isoquinolinones. R...

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Scheme 4: CN-K-catalyzed cyanomethylarylation of N-aryl acrylamides for the synthesis of oxindoles. Reaction ...

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Scheme 5: CN-K-catalyzed cyanomethylarylation of N-benzoyl acrylamides for the synthesis of isoquinolinedione...

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Figure 1: Evaluation of catalyst recycling. Reaction conditions: 1a (0.1 mmol, 1 equiv), 2d (0.2 mmol, 2 equi...

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Scheme 6: Further survey of reaction scope and derivatization studies of 8a.

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Scheme 7: Experiments for the mechanistic study.

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Scheme 8: Plausible mechanism of the CN-K-catalyzed cyanomethylarylation of alkenes.

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Published 17 May 2021

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